Innovative design of titanium alloy with supreme properties by 3D printing

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A research led by scientists from City University of Hong Kong (CityU) has successfully developed a super-strong, highly ductile and super-light titanium-based alloy using additive manufacturing, commonly known as 3D printing. Their findings open up a new pathway to design alloys with unprecedented structures and properties for various structural applications.  

The research team was led by Professor Liu Chain-Tsuan, University Distinguished Professor in the College of Engineering and Senior Fellow of CityU’s Hong Kong Institute for Advanced Study (HKIAS). Dr Zhang Tianlong, a postdoc in the Department of Materials Science and Engineering (MSE), conducted the experiments. Their paper was published recently in the prestigious scientific journal Science, titled “In situ design of advanced titanium alloy with concentration modulations by additive manufacturing”.

3D printing
The new titanium alloy developed by City University of Hong Kong using 3D printing has lava-like microstructures that give rise to its excellent mechanical properties.Credit: City University of Hong Kong

3D printing: not just a shaping technology

Most people consider 3D printing as a revolutionary technology that can produce machine parts with complex shapes within just one step. “However, we unveiled that it has important potential in designing materials rather than simply designing geometries,” said Dr Zhang, who completed his PhD at CityU under Professor Liu’s supervision earlier this year.

Metallurgists tend to think that a lack of uniformity in alloy components is undesirable because it leads to bad properties, such as brittleness. One of the key issues in the additive manufacturing process is how to eliminate this inhomogeneity during fast cooling. But Dr Zhang’s previous modelling and simulation study found that a certain degree of heterogeneity in the components can actually produce unique and heterogeneous microstructures that enhance the alloy’s properties. So he tried to put these simulation results into reality by using the additive manufacturing.

Designing unique microstructures

“The unique features of additive manufacturing provide us with a greater freedom in designing microstructures,” Dr Zhang explained, who is also the first author of the paper. “Specifically, we have developed a partial homogenisation method to produce alloys with micrometre-scale concentration gradients with the aid of 3D printing, which is unachievable by any conventional methods of material manufacturing.”

3D printing
Grain orientation map of the 3D-printed titanium alloy developed by the City University of Hong Kong research team.
Credit: Dr Zhang Tianlong /DOI number: 10.1126/science.abj3770

Their proposed method involves the melting and mixing of two different alloy, i.e. titanium alloy powders and stainless steel powders, using a focused laser beam. By controlling parameters like the laser power and its scanning speed during the 3D printing process, the team successfully created the non-uniform composition of the elements in the new alloy in a controllable way.

3D printing
Lava-like microstructure in 3D-printed titanium alloy developed by the research team led by City University of Hong Kong.
Credit: Dr Zhang Tianlong /DOI number: 10.1126/science.abj3770

“In addition to the use of additive manufacturing, the composition of the two powder mixture is another key to creating the unprecedented lava-like microstructures with a high metastability in the new alloy,” said Professor Liu. “These unique microstructures give rise to the supreme mechanical properties, allowing the alloy to be very strong but ductile, and in light weight.”

Novel alloy: 40% lighter and super-strong

3D printing
The experimental results show that the new titanium alloy has supreme mechanical properties.
Credit: Dr Zhang Tianlong /DOI number: 10.1126/science.abj3770

While stainless steel is generally 7.9 grammes per cubic centimetre, the new alloy is only 4.5 grammes per cubic centimetre, resulting in around 40% lighter weight. In their experiments, the titanium alloy with lava-like microstructures exhibited a high tensile strength of  ~1.3 gigapascals with a uniform elongation of about 9%. It also had an excellent work-hardening capacity of over 300 megapascals, which guarantees a large safety margin prior to fracture and is useful in structural applications.

“These excellent properties are promising for structural applications in various scenarios, such as the aerospace, automotive, chemical, and medical industries,” said Professor Liu.

“As the first team to use 3D printing to develop new alloys with unique microstructures and properties, we will further apply this design idea to different alloy systems to further explore other properties of the new alloys,” he added.

3D printing
Professor Liu Chain-Tsuan (left) and Dr Zhang Tianlong from City University of Hong Kong discuss the new pathway to design alloys by a 3D printing technique.
Credit: City University of Hong Kong


Professor Liu, Dr Yang Tao from MSE, and Professor Wang Yunzhi from The Ohio State University are the paper’s corresponding authors. Other CityU researchers who participated in the research included Dr Luan Junhua, Dr Wang Anding and Dr Kong Haojie. Other collaborators are Professor Huang Zhenghua from Guangdong Academy of Sciences and Dr Wang Dong from Xi'an Jiaotong University.

The research was supported by CityU, HKIAS, the National Key Research and Development Program of China, the National Natural Science Foundation of China, Guangdong Academy of Sciences, and the US National Science Foundation.

DOI number: 10.1126/science.abj3770

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