Contact Information

General Enquiry

Fax: +(852)-3442-0688
Address: G5703, 5/F, Yeung Kin Man Academic Building (YEUNG),
City University of Hong Kong,
Tat Chee Avenue, Kowloon, Hong Kong SAR
Multiphase Chemistry of Organic Aerosols and Reactive Oxygen Species
Speaker Name
Dr Manabu Shiraiwa
Speaker Detail

Assistant Professor
Department of Chemistry
University of California, Irvine

B5-309, 5/F, Yeung Kin Man Academic Building, City University of Hong Kong, Kowloon Tong, Kowloon, Hong Kong

Organizer: School of Energy and Environment
City University of Hong Kong



Multiphase chemical processes of oxidants and aerosol particles are of central importance in aerosol effects on outdoor and indoor air quality and public health. Kinetic multi-layer models for gas-particle interactions and multiphase chemistry have been developed that explicitly treat mass transport and chemical reaction of semi-volatile species partitioning between gas and condensed phases. These models have been applied to gas uptake and chemical aging of organic aerosols as well as formation and evolution of secondary organic aerosols. Secondary organic aerosols (SOA) are ubiquitous in the atmosphere. SOA can occur in amorphous solid or semi-solid phase states depending on chemical composition, relative humidity (RH), and temperature. The phase state of SOA is important for their effects on climate and air quality, but its global distribution is poorly characterized. Our analysis of SOA phase state builds on the molecular corridor approach, which is a two-dimensional framework of volatility and molar mass of SOA components constrained by boundary lines of low and high molecular O:C ratio. We developed a method to estimate glass transition temperatures based on the molar mass and molecular O:C ratio of SOA components. We predict viscosity from the Tg-scaled Arrhenius plot of fragility as a function of the fragility parameter. Viscosity of toluene SOA was predicted using the elemental composition obtained by high-resolution mass spectrometry (HRMS), resulting in a good agreement with the measured viscosity. Further, we used the global chemistry climate model EMAC with the organic aerosol module ORACLE to predict the phase state of atmospheric SOA. For the planetary boundary layer, global simulations indicate that SOA are mostly liquid in tropical and polar air with high relative humidity, semi-solid in the mid-latitudes, and solid over dry lands. We find that in the middle and upper troposphere SOA should be mostly in a glassy solid phase state. Thus, slow diffusion of water, oxidants, and organic molecules could kinetically limit gas-particle interactions of SOA in the free and upper troposphere, promote ice nucleation and facilitate long-range transport of reactive and toxic organic pollutants embedded in SOA.

About the Speaker

Dr Manabu Shiraiwa is Assistant Professor of Chemistry at the University of California, Irvine. He has worked as group leader at the Max Planck Institute for Chemistry (2013-2016) and as JSPS postdoc fellow at the California Institute of Technology (2012-2013). He received BS and MS at the University of Tokyo and PhD from the Max Planck Institute for Chemistry.