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Prof. KO Chi Chiu Vincent
高志釗教授
PhD (HK)

Professor of Department of Chemistry


Contact Information
Office: YEUNG-B6515
Phone: +852 3442-6958
Fax: +852 3442-0522
Email: vinccko@cityu.edu.hk
Web: Personal Homepage
ORCID ID: 0000-0002-2426-3206
Scopus Author ID: 57288331300
Research Interests
  • Inorganic and Organometallic Chemistry
  • Photocatalysis
  • Photochemistry
  • Photoswitching and Photochromic Material

Prof. Vincent Ko received his B. Sc. (1999) and Ph. D. (2003) from the University of Hong Kong. His Ph. D. works mainly focused on the designs, syntheses, photophysics, and photochemical studies of metal-containing photochromic compounds and luminescent organometallic compounds. After his doctoral study, he continued to work as a Postdoctoral Fellow with Prof. Vivian Yam. He joined City University of Hong Kong in September 2006. His current research interests include the design and synthesis of luminescence, photoswitching and photochromic materials, and functionalization of these molecular materials towards the design of photo-regulated active transporters, scavengers, chemosensors, smart surfaces and devices.

Publications
  • R. Liu; S.-C. Cheng; Y. Xiao; K.-C. Chan; K.-M. Tong, C.-C. Ko, “Recyclable Polymer-Supported Iridium-Based Photocatalysts for Photoredox Organic Transformations”, in J. Catal. 2022, 407, 206-212.
  • J. Han, S.-C. Cheng, S.-M. Yiu, M.-K. Tse, C.-C. Ko, “Luminescent Monomeric and Dimeric Ru(II) Acyclic Carbene Complexes as Selective Sensors for NH3/Amine Vapor and Humidity”, in Chem. Sci. 2021, 12, 14103-14110.
  • J. Han, Y.-K. Chun, S.-L. Chan, S.-C. Cheng, S.-M. Yiu, C.-C. Ko, “Development of Dual Phosphorescent Materials Based on Multiple Stimuli-Responsive Ir(III) Acyclic Carbene Complexes”, in CCS Chem, 2021, 3, 2345-2359.
  • Y.-L. Xiao, Y.-K. Chun, S.-C. Cheng, C.-O. Ng, M.-K. Tse, E. N.-Y. Lei, R.-Y. Liu, C.-C. Ko, “Photocatalytic Amidation and Esterification with Perfluoroalkyl Iodide”, in Catal. Sci. Technol., 2021, 11, 556-562.
  • C.-L. Kwok, S.-C. Cheng, P.-Y. Ho, S.-M. Yiu, W.-L. Man, P.-K. Tsang, C.-F. Leung, C.-C. Ko, M. Robert, “Precious-metal free Photocatalytic Production of an NADH Analogue using Cobalt Diimine-dioxime Catalysts in both Aqueous and Organic Conditions”, in Chem. Commun. 2020, 56, 7491-7494.
  • J. Han, K.-M. Tang, S.-C. Cheng, C.-O. Ng, Y.-K. Chun, S.-L. Chan, S.-M. Yiu, M.-K. Tse, V. A. L. Roy, C.-C. Ko, “Mechanochemical Changes on Cyclometalated Ir(III) Acyclic Carbene Complexes - Design and Tuning of Luminescent Mechanochromic Transition Metal Complexes”, in Inorg. Chem. Front., 2020, 7, 786-794.
  • K.-C. Chan, K.-M. Tong, S.-C. Cheng, C.-O. Ng, S.-M. Yiu, C.-C. Ko, “Design of Luminescent Isocyano Rhenium(I) Complexes: Photophysics and Effects of the Ancillary Ligands”, in Inorg. Chem., 2018, 57, 13963-13972.
  • B. Kandasamy, G. Ramar, L. Zhou, S.-T. Han, S. Venkatesh, S.-C. Cheng, Z.-X. Xu, C.-C. Ko, V. A. L. Roy, “Polypyridyl Chromium(III) Complexes for Non-Volatile Memory Application: Impact of Coordination Sphere on Memory Device Performance”, in J. Mater. Chem. C, 2018, 6, 1445-1450.
  • C.-C. Ko, V. W.-W. Yam, “Coordination Compounds with Photochromic Ligands: Ready Tunability and Visible Light-Sensitized Photochromism”, in Acc. Chem. Res., 2018, 1, 149-159.
  • Z.-G. Guo, S.-W. Cheng, C. Cometto, E. Anxolabéhère-Mallart, S.-M. Ng, C.-C. Ko, G.-J. Liu, L.-J. Chen, M. Robert, T.-C. Lau, “Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes”, in J. Am. Chem. Soc., 2016, 138, 9413-9416.
  • C.-O. Ng, S.-C. Cheng, W.-K. Chu, K.-M. Tang, S.-M. Yiu, C.-C. Ko, “Luminescent Rhenium(I) Pyridyl-Diaminocarbene Complexes - Photophysics, Anion Binding and CO2 Capturing Properties”, in Inorg. Chem., 2016, 55, 7969-7979.
  • A. Maurin, C.-O. Ng, L.-J. Chen, T.-C. Lau, M. Robert, C.-C. Ko, “Photochemical and Electrochemical Catalytic Reduction of CO2 with NHC-Containing Dicarbonyl Rhenium(I) Bipyridine Complexes”, in Dalton Trans., 2016, 45, 14524-14529.
  • L. Ma, Q. Wang, W.-L. Man, H.-K. Kwong, C.-C. Ko, T.-C. Lau, “CeIV-Driven Water Oxidation Catalyzed by a Manganese(V) Nitrido Complex”, in Angew. Chem. Int. Ed., 2015, 54, 5246-5249.
  • W.-K. Chu, X.-G. Wei, S.-M. Yiu, C.-C. Ko, K.-C. Lau, “Strongly Phosphorescent Neutral Rhenium(I) Isocyanoborato Complexes: Synthesis, Characterization, and Photophysical, Electrochemical, and Computational Studies”, in Chem. Eur. J., 2015, 21, 2603-2612.
  • W.-K. Chu, C.-C. Ko, K.-C. Chan, S.-M. Yiu, F.-L. Wong, C.-S. Lee, V. A. L. Roy, “A Simple Design for Strongly Emissive Sky-Blue Phosphorescent Neutral Rhenium Complexes: Synthesis, Photophysics and Electroluminescent Devices”, in Chem. Mater., 2014, 26, 2544-2550.
  • H. Feng, F. Zhang, S.-W. Lai, S.-M. Yiu, C.-C. Ko, “Luminescent Cyanoruthenate(II) and Cyanoruthenium(II) Diimine Complexes”, in Chem. Eur. J., 2013, 19, 15190-15198.
  • L. T.-L. Lo, S.-W. Lai, S.-M. Yiu, C.-C. Ko, “New Class of Highly Solvatochromic Dicyano Rhenate(I) Diimine Complexes - Synthesis, Photophysics and Photocatalysis”, in Chem. Commun., 2013, 49, 2311-2313.
  • C.-F. Leung, S.-M. Ng, C.-C. Ko, W.-L. Man, J.-S. Wu, L.-J. Chen, T.-C. Lau, “A Cobalt(II) Quaterpyridine Complex As a Visible Light-Driven Catalyst for Both Water Oxidation and Reduction”, in Energy Environ. Sci., 2012, 5, 7903-7907.
  • C.-C. Ko, A. W.-Y. Cheung, L. T.-L. Lo, J. W.-K. Siu, C.-O. Ng, S.-M. Yiu, “Synthesis and Photophysical Study of New Classes of Luminescent Isocyano Rhenium(I) Diimine Complexes”, invited contribution to Coord. Chem. Rev., 2012, 256, 1546-1555.
  • C.-C. Ko, L. T.-L. Lo, C.-O. Ng, S.-M. Yiu, “Photochemical Synthesis Of Intensely Luminescent Isocyano Rhenium(I) Complexes With Readily Tunable Structural Feature” in Chem.-Eur. J, 2010, 16, 13773-13782.
  • C.-O. Ng, L. T.-L. Lo, S.-M. Ng, C.-C. Ko, N. Zhu, “A New Class of Isocyanide-Containing Rhenium(I) Bipyridyl Luminophore with Readily Tunable and Highly Environmentally Sensitive Excited-State Properties” in Inorg. Chem., 2008, 47, 7447-7449.
  • C.-C. Ko, W.-M. Kwok, V. W.-W. Yam, D. L. Phillips, “Triplet MLCT Photosensitization of Ring-Closing Reaction of Diarylethenes Via the Design and Synthesis of a Photochromic Rhenium(I) Diarylethene-Containing 1,10-Phenanthroline Complex” in Chem. Eur. J., 2006, 12, 5840-5848.
  • V. W.-W. Yam, C.-C. Ko, N. Zhu, “Photochromic and Luminescence Switching Properties of A Versatile Diarylethene-Containing 1,10-Phenanthroline Ligand and Its Rhenium(I) Complex” in J. Am. Chem. Soc., 2004, 126, 12734-12735