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3D Liquid Diode and Permeable Electronic Devices Based on the Same

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Opportunity

 Wearable electronics have revolutionized personal health monitoring by enabling noninvasive tracking of bio-signals and environmental conditions, offering immense potential for early disease detection, diagnostics, and sports health management. However, a critical barrier to their widespread adoption and long-term user compliance is comfort, particularly under real-world conditions where sweating occurs. Existing wearable devices often compromise on permeability to integrate functionality, leading to significant discomfort. Materials like polydimethylsiloxane (PDMS), while flexible, exhibit poor vapor and sweat permeability. This results in sweat accumulation at the skin-device interface, causing skin irritation, reduced adhesion, unstable signal acquisition, and thermal discomfort. Furthermore, achieving both high permeability and multifunctional electronic integration in a single, comfortable system remains an unresolved challenge. The market lacks a wearable platform that can effectively manage perspiration while maintaining robust electronic performance, stable skin adhesion, and long-term wearability without causing cutaneous issues.

Technology

The invention addresses these challenges by introducing a novel three-dimensional (3D) liquid diode structure that enables directional, spontaneous, and rapid fluid transport. The core innovation is a multi-layered architecture comprising a vertical liquid diode layer, a horizontal liquid diode layer, and an intermediate liquid collector. The vertical layer is fabricated from a hydrophilic polyester fabric treated to create a vertical hydrophilicity gradient within its microchannels. This gradient, achieved through selective oxygen plasma treatment after superhydrophobic coating, makes the top of each channel more hydrophilic than the bottom, enabling autonomous upward pumping of sweat from the skin. Above this, the horizontal layer is made from PDMS patterned with an array of super-hydrophilic micropillars arranged with a horizontal structural gradient—specifically, a gradient of spacing distances. This gradient directs the sweat laterally from the central regions (aligned with the vertical channels) toward the periphery. The liquid collector, positioned between these layers, couples with outlets surrounding the micropillars to collect and discharge the transported sweat. This integrated 3D design facilitates rapid, self-powered sweat transport at a rate of 12.6 ml/cm²/min from the skin interface to the exterior, preventing backflow and maintaining a dry, comfortable interface. The platform is inherently thin, soft, stretchable, and waterproof. Crucially, it serves as a foundational substrate for building permeable electronic devices. For instance, permeable bio-signal monitoring devices integrate open-mesh, serpentine-shaped electrodes at the bottom of the vertical layer for signal acquisition, while magnetic coupling elements embedded in the horizontal layer allow for detachable, reusable flexible circuit boards containing microcontrollers and communication modules. Similarly, the platform can be integrated into textiles to create personal weather stations with embedded environmental sensors. The technology maintains its sweat-pumping performance under various mechanical deformations such as bending and stretching, ensuring reliability during user movement.

Advantages

  • Superior Sweat Management: Enables rapid, directional sweat transport (12.6 ml/cm²/min) away from the skin-device interface, preventing accumulation and backflow.
  • Enhanced Wearer Comfort: Significantly improves vapor and sweat permeability, reducing skin temperature rise, irritation, and discomfort during long-term wear, even during intense physical activity.
  • Stable Device Performance: Maintains robust and stable adhesion to the skin under sweating conditions, unlike conventional patches which often detach.
  • High-Quality Signal Acquisition: Permeable electrodes integrated with the 3D diode provide stable, high-signal-to-noise-ratio bio-signals (e.g., ECG) during both rest and sweating states, overcoming signal degradation common in impermeable devices.
  • Mechanical Robustness and Conformability: The structure remains functional under convex/concave bending and stretching, ensuring reliable performance during user motion.
  • Modular and Reconfigurable Design: The magnetic coupling mechanism allows the electronic circuit board to be detachable, promoting reusability, easy maintenance, and cost reduction.
  • Biocompatibility and Skin Safety: Demonstrated excellent biocompatibility in cytotoxicity assessments, causing no skin erythema or irritation during extended wear.
  • Platform Versatility: Serves as a foundational, permeable substrate for integrating diverse electronic functionalities, from bio-sensing to environmental monitoring.

Applications

  • Long-term Health Monitoring Wearables: For continuous, comfortable monitoring of electrocardiogram (ECG), heart rate, heart rate variability, and other bio-signals in daily life and during exercise.
  • Sports and Fitness Electronics: Integrated into sportswear or patches for athletes to monitor physiology without discomfort from sweat, enabling performance optimization.
  • Clinical and Remote Patient Monitoring: Provides a comfortable solution for patients requiring prolonged bio-signal tracking, improving compliance and data reliability.
  • Smart Textiles and E-Textiles: Integration into fabrics for wearable personal weather stations that monitor ambient temperature, humidity, UV index, and atmospheric pressure.
  • Advanced Military and Occupational Gear: For personnel in high-stress, high-activity environments where sweat management and physiological monitoring are critical.
  • Reusable Diagnostic Patches: The detachable electronics design allows the more expensive circuit components to be reused with disposable or washable substrate patches.
  • Consumer Wellness Devices: For everyday health and activity tracking in form factors that prioritize skin comfort and breathability.
Remarks
IDF:1562
IP Status
Patent filed
Technology Readiness Level (TRL)
4
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3D Liquid Diode and Permeable Electronic Devices Based on the Same

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