Prof. Michael C W CHAN

PhD (Durham)

Professor of Department of Chemistry

 

Contact Information

Office: YEUNG-G6615
Phone: +852 3442-9678
Email:  mcwchan@cityu.edu.hk
ORCID ID: 0000-0002-2997-8577
Scopus
Author ID:
29067669100

Research Interests

See below.

Michael Chan was born in Hong Kong, and emigrated to England in 1978. He received his Ph.D. in 1995 from Durham University under the tutelage of Prof. Vernon C. Gibson FRS (Imperial) in the field of catalyst design and polymerization technology. His studies continued as a post-doctoral fellow with Prof. Chi-Ming Che in the area of light-emitting materials at the University of Hong Kong, where he was appointed Research Assistant Professor in 1998. He joined City University of Hong Kong as an Assistant Professor in 2004, and was promoted through the ranks to Professor in 2018.    

He received the 2007 Mitsui Chemicals Catalysis Science Award of Encouragement. He presented Keynote Lectures at 16th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC-16), Sapporo, Japan in August 2013, and 19th International Symposium on Fluorine Chemistry (19thISFC-ISoFT'09), Jackson Hole, Wyoming, USA in August 2009. He was a Symposium Co-organizer for "Polyolefins Chemistry and Beyond - From Bench To Commercial Scale" (Symposium #211) at Pacifichem 2010, Honolulu, Hawaii, in December 2010, and has undertaken Visiting Professorships at University of Münster (2007 and 2011), Kyoto University (2010), and Osaka University (2014 and 2018).

His papers on C-H···F-C interactions in post-metallocene catalysts have been selected as Cover Pictures in Chemistry – A European Journal, and an overview was published in Accounts of Chemical Research in 2015. He has been actively engaged in collaborative research on olefin polymerization catalysts with industrial partners since 2000, and has obtained 8 international patents.


Positions Available in Catalysis/Supramolecular/Organometallic Chemistry

PhD studentships are available in topics including (but not limited to): coordination/organometallic (Schlenk-type)/supramolecular chemistry and/or homogeneous catalysis. 

PhD candidates must have a good MPhil or BSc degree in chemistry, and proven English proficiency (TOEFL: minimum score of 550 (paper) / 213 (computer) / 79 (internet); or IELTS: overall band score of 6.5). The ideal candidate should display good problem-solving skills and creativity, and possess a strong background/experience in synthetic (organic/coordination) chemistry. 

PhD applications should be made asap (applications will be accepted until all positions are filled). For initial enquiries, please contact Prof. Chan by email and include a full CV with contact details of referees.

Research Interests and Projects

The following topics, underpinned by utilization of supramolecular strategies, are under investigation:
(1) design of novel catalyst systems for polymerization reactions, and development of 'weak attractive ligand–polymer interactions' in catalysis;
(2) crowded and shape-persistent luminescent molecular and polymeric architectures exhibiting unusual photophysical and conformational properties;
(3) development of 'shape-persistent bimetallic design' approach for catalytic production of valuable feedstock and polymers from sustainable resources.


 


     

Selected Publications

  1. Olefin Polymerization Reactivity of Group 4 Post-Metallocene Catalysts Bearing a Four-Membered C(sp3)-Donor Chelate Ring, C.-C. Liu, Q. Liu, P.-K. Lo, K.-C. Lau, S.-M. Yiu, M. C. W. Chan, ChemCatChem, 2019, 11, 628635. DOI: 10.1002/cctc.201801008

  2. Poly(Zn-salphen)-alt-(p-phenyleneethynylene)s as Dynamic Helical Metallopolymers: Luminescent Properties and Conformational Behavior, C. Zhao, S. Sun, W.-L. Tong, M. C. W. Chan, Macromolecules, 2017, 50, 6896–6902. DOI: 10.1021/acs.macromol.7b01269

  3. Multifaceted Chelating μ-(η33-antifacial)-(cis-C4R2H2) Coordination Motif in Binuclear Complexes, C.-C. Liu, M. C. W. Chan, P.-K. Lo, K.-C. Lau, S.-M. Yiu, Chem. Commun., 2016, 52, 11056–11059 (Cover Article; Inside). DOI: 10.1039/c6cc05535d

  4. Topologically Diverse Shape-Persistent Bis-(Zn-salphen) Catalysts: Efficient Cyclic Carbonate Formation under Mild Conditions, S. He, F. Wang, W.-L. Tong, S.-M. Yiu, M. C. W. Chan, Chem. Commun., 2016, 52, 1017–1020. DOI: 10.1039/c5cc08794e

  5. Chelating σ-Aryl Post-Metallocenes: Probing Intramolecular [C–H···F–C] Interactions and Unusual Reaction Pathways, C.-C. Liu, M. C. W. Chan, Acc. Chem. Res., 2015, 48, 1580–1590. DOI: 10.1021/acs.accounts.5b00008 

  6. Luminescent Oligo(ethylene glycol)-Functionalized Cyclometalated Platinum(II) Complexes: Cellular Characterization and Mitochondria-Specific Localization, Z. Guo, W.-L. Tong, M. C. W. Chan, Chem. Commun., 2014, 50, 1711–1714. DOI: 10.1039/c3cc47150k

  7. Shape-Persistent (Pt-salphen)2 Phosphorescent Coordination Frameworks: Structural Insights and Selective Perturbations, Z. Guo, S.-M. Yiu, M. C. W. Chan, Chem. Eur. J., 2013, 19, 8937–8947. DOI: 10.1002/chem.201300421

  8. Crowded Bis-(M-salphen) [M = Pt(II), Zn(II)] Coordination Architectures: Luminescent Properties and Ion-Selective Responses, W.-L. Tong, S.-M. Yiu, M. C. W. Chan, Inorg. Chem., 2013, 52, 7114–7124. DOI: 10.1021/ic400692x

  9. Olefin Polymerization Behavior of Titanium(IV) Pyridine-2-phenolate-6-(σ-aryl) Catalysts: Impact of ‘py-Adjacent’ and Phenolate Substituents, J. C. Y. Lo, M. C. W. Chan, P.-K. Lo, K.-C. Lau, T. Ochiai, H. Makio, Organometallics, 2013, 32, 449–459. DOI: 10.1021/om300832q

  10. Scalar Coupling Across [C-H···F-C] Interactions in (σ-Aryl)-Chelating Post-Metallocenes, L.-C. So, C.-C. Liu, M. C. W. Chan, J. C. Y. Lo, K.-H. Sze, N. Zhu, Chem. Eur. J., 2012, 18, 565–573 (Cover Picture). DOI: 10.1002/chem.201102439

  11. Congested Cyclometalated Platinum(II) Ditopic Frameworks and Their Phosphorescent Responses to S-Containing Amino Acids, W.-L. Tong, M. C. W. Chan, S.-M. Yiu, Organometallics, 2010, 29, 6377–6383. DOI: 10.1021/om1007488

  12. Alternating Poly(Pt-salphen)-(p-phenyleneethynylene) as Phosphorescent Conjugated Linear-Rod and Coilable Sensory Materials, S. Sun, W.-L. Tong, M. C. W. Chan, Macromol. Rapid Commun., 2010, 31, 1965–1969. DOI: 10.1002/marc.201000266

  13. Shape-Persistent Binuclear Cyclometalated Pt(II) Luminophores: Pushing π-Mediated Excimeric Fluid Emissions into the NIR Region and Ion-Induced Perturbations, Z. Guo, M. C. W. Chan, Chem. Eur. J., 2009, 15, 12585–12588. DOI: 10.1002/chem.200902328

  14. Neutron and X-Ray Diffraction and Spectroscopic Investigations of Intramolecular [C-H···F-C] Contacts in Post-Metallocene Polyolefin Catalysts: Modeling Weak Attractive Polymer–Ligand Interactions, M. C. W. Chan, S. C. F. Kui, J. M. Cole, G. J. McIntyre, S. Matsui, N. Zhu, K.-H. Tam, Chem. Eur. J., 2006, 12, 26072619 (Cover Picture). DOI: 10.1002/chem.200501054

  15. Observation of Intramolecular [C-H···F-C] Contacts in Non-Metallocene Polyolefin Catalysts: Model for Weak Attractive Interactions between Polymer Chain and Non-Innocent Ligand, S. C. F. Kui, N. Zhu, M. C. W. Chan, Angew. Chem. Int. Ed., 2003, 42, 16281632. DOI: 10.1002/anie.200219832