Ice Surface: Insights from Recent Study

Date: 26 June 2015
Speaker: 王恩哥教授
Prof. Wang Enge


Despite ice being a ubiquitous and well-studied substance, it is surprising that some basic questions about its surface properties are still debated. Here the recent study of the unusual structure and dynamics of ice surface is discussed at atomic scale. An order parameter, which defines the ice surface energy, is identified for the first time. A classical electrostatic model proves useful to explain the physics inside. We predict that the proton order-disorder transition, which occurs in the bulk at ~72 K, will not occur at the surface at any temperature below surface melting. In addition, it is found that vacancy energy to be as low as ~0.1eV at the surface, leading to a higher than expected concentration of vacancies at the external layer. Once a surface vacancy is formed, the energetic cost of forming neighbouring vacancies is greatly reduced, facilitating pits on the surface and other processes that may contribute to the phenomenon of pre-melting and quasi-liquid layer formation. Finally, we show that the distribution of local arrangement of dangling atoms is of crucial importance for the adsorption of water monomer on ice surface. The positive correlation of adsorption energy of water monomer with surface proton ordering suggests that the adsorption may prefer to firstly occur in the inhomogeneous surface, which sheds light on our understanding of the ice nucleation and growth as well as other physical/chemical reactivity in high altitude clouds.

Speaker Bio

Prof. Wang Enge

Vice President of the Chinese Academy of Sciences
Chair Professor of Physics, Peking University





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